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Vim li cas peb thiaj xav tau benzoin condensation?

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Vim li cas peb thiaj xav tau benzoin condensation?
Vim li cas peb thiaj xav tau benzoin condensation?

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Video: Vim li cas peb thiaj xav tau benzoin condensation?
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Kev siv thiab kev siv ntawm Benzoin Condensation Cov tshuaj tiv thaiv yog pab tau rau hauv kev sib txuas ntawm heterocyclic compounds thiab tseem txuas mus rau aliphatic daim ntawv ntawm aldehydesCov tshuaj tiv thaiv kuj pom nws daim ntawv thov hauv cov organic chemistry rau zus tau tej cov polymers thiab nyob rau hauv condensation ntawm tshiab monomers.

Lub hom phiaj ntawm benzoin condensation yog dab tsi?

Cov Benzoin Condensation yog kev sib txuas lus ntawm ob aldehydes uas tso cai rau kev npaj ntawm α-hydroxyketones. Thawj txoj hauv kev tsuas yog tsim nyog rau kev hloov pauv ntawm aromatic aldehydes.

Dab tsi yog benzoin condensation muab piv txwv?

Hint: 1) Hauv Benzoin condensation yog ib qho tshuaj tiv thaiv ntxiv uas muaj ob lub aldehydes. Cov tshuaj tiv thaiv feem ntau tshwm sim ntawm ob qho tshuaj tsw qab aldehydes ntawm glyorals. … Ib qho piv txwv ntawm cov tshuaj tiv thaiv no yog thaum benzaldehyde condenses nrog malonic acid nyob rau hauv muaj pyridine ua ib qho yooj yim catalyst

Dab tsi yog cov catalyst siv hauv benzoin condensation?

Ib qho piv txwv classic yog benzoin condensation, thawj zaug tshaj tawm los ntawm Wöhler thiab Liebig hauv 1832 nrog cov txheej txheem npaj rau xyoo 1903 los ntawm Lapworth; cyanide yog siv los ua ib qho kev cuam tshuam los cuam tshuam lub dimerization ntawm ob chav benzaldehyde [13]. Xyoo 1943, Ukai et al. nrhiav tau lub peev xwm ntawm thiazolium ntsev rau catalyze lub condensation.

Leej twg nrhiav tau benzoin condensation?

3. Cov txiaj ntsig thiab kev sib tham. Benzoin condensation yog ib qho kev paub zoo ntawm cov khoom siv hluavtaws ua rau muaj kev ntxim nyiam α-hydroxy-carbonyls. Liebig xyoo 1832 thawj zaug pom cov benzoin condensation catalyzed los ntawm cyanide ntsev (Wöhler thiab Liebig, 1832).

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